Show simple item record Boeré, René T. Ferguson, George Oakley, Richard T. 2015-11-25T21:46:34Z 2015-11-25T21:46:34Z 1986
dc.identifier.citation Boere, R. T., Ferguson, G., & Oakley, R. T. (1986). Structure of an eight-membered CN4S3 ring with a Ph3P=N substituent. Acta Crystallographica Section C, Crystal Structure Communications, C42, 900-902. en_US
dc.description Sherpa Romeo green journal en_US
dc.description.abstract 7-Phenyl-3-(triphenylphosphinimino)- 1,3,5,- 2,4,6,8-trithiatetrazocine, C25H20N5PS3, Mr = 517.64, monoclinic, P21/c, a = 13.957 (3), b = 9.242 (3), c = 19.473 (4)/k, fl= 102.80 (2) °, V= 2449.4 A 3, Z =4, Dx=l.4Ogcm -3, 2(MoKc0=0.71069A, ~= 3.8cm -1, F(000)=1072, T=293(1) K, final R= 0.038 for 2430 observed reflections. The molecule has a phenyl ring substituted at a planar carbon, and a PhaP=N group substituted at S in the 3-position. The CN4S3 ring is folded by 114.5 °, with an almost planar SNCNS fragment, and an endo-S-envelope SNSNS fragment (dihedral 145.0°). The PhaP=N substituent at S is endo and the transannular S...S contact is 2.415 (1)A. en_US
dc.language.iso en_CA en_US
dc.publisher International Union of Crystallography en_US
dc.title Structure of an eight-membered CN4S3 ring with a Ph3P=N substituent en_US
dc.type Article en_US
dc.publisher.faculty en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution University of Guelph en_US

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