Show simple item record Drescher, Sam L. Forfar, Christopher P. Boeré, René T. Hayes, Paul G. 2022-08-16T19:53:41Z 2022-08-16T19:53:41Z 2021
dc.identifier.citation Drescher, S. L., Forfar, C. P., Boeré, R. T., & Hayes, P. G. (2021). X-ray crystal structure of [L2Ag3]+[OTf]−·5C6D6: a monoanionic bis­­phosphinimine ligand supported tris­­ilver complex. Acta Crystallographica, Section E: Crystallographic Communications, E77(10), 1025-1028. en_US
dc.description Open access article. Creative Commons Attribution 4.0 International License (CC BY 4.0) applies en_US
dc.description.abstract The compound bis­{μ3-2,5-bis­[N-(4-iso­propyl­phen­yl)-P,P-di­phenyl­phospho­r­im­i­do­yl]pyrrol-1-ido-κ3N:N′:N′′}tris­ilver(I) tri­fluoro­methane­sulfonate deuterated benzene penta­solvate, [Ag3(C46H44N3P2)2](CF3O3S)·5C6D6, (I), was synthesized from two equivalents of NaL [L = 2,5-(4-iPrC6H4N=PPh2)C4H2N] and three equivalents of AgOTf (OTf = OSO2CF3). High-quality crystals of (I) formed with five deuterated benzene solvent mol­ecules in the asymmetric unit. Notably, the bond lengths and angles between the three silver atoms are markedly different, unlike in most other reported tris­ilver complexes that tend to form three equivalent metal centers. Additionally, to the best of our knowledge, this is the first report of a tris­ilver complex with six nitro­gen donors from two bis­phosphinimine ligands. en_US
dc.language.iso en_US en_US
dc.subject X-ray crystal structure en_US
dc.subject Phosphinimine en_US
dc.subject Trisilver en_US
dc.subject Monoanionic en_US
dc.subject.lcsh X-ray crystallography
dc.title X-ray crystal structure of [L2Ag3]+[OTf]−·5C6D6: a monoanionic bis­­phosphinimine ligand supported tris­­ilver complex en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution University of Lethbridge en_US
dc.publisher.url en_US

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