Show simple item record Ramachandran, Mridhul R. K. Schnakenburg, Gregor Majumdar, Moumita Kelemen, Zsolt Gal, Dalma Nyulaszi, Laszlo Boeré, René T. Streubel, Rainer K. 2022-08-16T20:25:00Z 2022-08-16T20:25:00Z 2022
dc.identifier.citation Ramachandran, M. R. K., Schnakenburg, G., Majumdar, M., Kelemen, Z., Gal, D., Nyulaszi, L., Boeré, R. T., & Streubel, R. K. (2022). Reversible redox chemistry of anionic imadazole-2-thione-fused 1,4-dihydro-1,4-diphosphinines. Inorganic Chemistry, 61(11), 4639-4646. en_US
dc.description Open access article. Creative Commons Attribution 4.0 International License (CC BY 4.0) applies en_US
dc.description.abstract Anionic 1,4-dihydro-1,4-diphosphinines were synthesized from tricyclic 1,4-diphosphinines and isolated as blue powdery salts M[2a–2c]. Reaction of solutions of these monoanions with iodomethane led to P-methylated compounds 3a–3c. An oxidation/reduction cycle was examined, starting from solutions of K[2a] via P–P coupled product 4a and back to K[2a], and the recyclability and redox chemistry of this cycle were confirmed by experimental and simulated cyclic voltammetry analysis, which is proposed as a potential 2-electron cathode for rechargeable cells. TD-DFT studies were used to examine species that might be involved in the process. en_US
dc.language.iso en_US en_US
dc.publisher ACS Publications en_US
dc.subject Redox reactions en_US
dc.subject.lcsh Color
dc.subject.lcsh Electrodes
dc.subject.lcsh Ethers
dc.subject.lcsh Molecular structure
dc.subject.lcsh Oxidation-reduction reaction
dc.title Reversible redox chemistry of anionic imidazole-2-thione-fused 1,4-dihydro-1,4-diphosphinines en_US
dc.type Article en_US
dc.publisher.faculty Arts and Science en_US
dc.publisher.department Department of Chemistry and Biochemistry en_US
dc.description.peer-review Yes en_US
dc.publisher.institution Rheinische Friedrich-Wilhelms-Universitat Bonn en_US
dc.publisher.institution Indian Institute of Science Education and Research en_US
dc.publisher.institution Budapest University of Technology and Economics en_US
dc.publisher.institution University of Lethbridge en_US
dc.publisher.url en_US

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